Visio P&ID is to draw ...

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Visio P&ID is to draw documents.

'Activated sludge expert' appears to be discontinued.

 

I think your best bet is the *non-free* software from EnviroSim Associates, PetWin.

 

Failing that you can try using the municipal wastewater treatment plant software, but be aware that they are set up for a different system - no sulphides, little handling of inhibition, ...